Abstract

ARC de triomphe: Ortho-TMS benzaldehyde permits efficient multicomponent union of a variety of nucleophiles and electrophiles, including the first example of a Pd-mediated ARC Type II process. A “proof-of-concept” synthetic sequence was designed and implemented for construction of a focused library of “natural product-like” compounds (see scheme). ARC: anion relay chemistry. Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2002/2008/z802301_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.

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