Abstract

A new series of organometallic complexes has been prepared by the reaction of acetylene and acetylene derivatives with carbonyls of the transition metals. A given carbonyl-acetylene system may yield as many as seven different complexes which are generally well crystallized, stable and soluble in organic solvents. It appears that these compounds are generally π-complexes in which the organic portion, usually a conjugated ring structure, is linked to the metal-carbonyl portion by the sort of interaction now familiar from aromatic and diene complexes.

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