Abstract
Recent studies with Andisols show that the carbon (C) stabilization capacity evolves with soil age relative to the evolution of the mineral phase. However, it is not clear how soil mineralogical changes during pedogenesis are related to the composition of soil organic matter (SOM) and 14C activity as an indicator for the mean residence time of soil organic matter (SOM). In the present study, we analyzed the contribution of allophane and metal–SOM complexes to soil C stabilization. Soil organic matter was analyzed with solid-state 13C nuclear magnetic resonance spectroscopy. Additionally, the soil was extracted with Na-pyrophosphate (Alp, Fep) and oxalate (Alo, Sio, and Feo). Results supported the hypothesis that allophane plays a key role for SOM stabilization in deep and oldest soil, while SOM stabilization by metal (Al and Fe) complexation is more important in the surface horizons and in younger soils. The metal/Cp ratio (Cp extracted in Na-pyrophosphate), soil pH, and radiocarbon age seemed to be important indicators for formation of SOM–metal complexes or allophane in top- and subsoils of Andisols. Changes in main mineral stabilization agents with soil age do not influence SOM composition. We suggest that the combination of several chemical parameters (Alp, Fep and Cp, metal/Cp ratio, and pH) which change through soil age controls SOM stabilization.
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