Abstract
Reactions of p- bromoacetanilide (benzanilide) with ammonium salt of alkylene dithiophosphates NH4 +; G =-CMe2CMe2-, -CH2CMe2CH2-, -CMe2CH2CHMe-, CH2CH2CHMe-) in 1:1 molar ratio in refluxing benzene solution yields; acetanilide (benzanilide) derivatives of alkylene dithiophosphates, OGOP(S)S C6H4NH COR (R = Me or Ph). The newly synthesized derivatives have been characterized by elemental analysis, molecular weight determination, IR, NMR (1H & 31P) spectral studies. In contrast to bidentate behavior in metal and organometal derivatives of alkylene dithiophosphate (adttp), the behavior of the dithiophosphato moiety in these derivatives is found to be monodentate. On the basis of above studies the formation of P(S)S-C linkage have been established.
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