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https://doi.org/10.1039/c5ob01301a
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Cite Journal: Org. Biomol. Chem. |  Publication Date: Jan 1, 2015 |
 Citations: 44 |
Highly enantioselective cyanation of β-keto esters using hypervalent iodine(iii) as the electrophilic cyanating reagent induced by cinchona alkaloid-based chiral quaternary ammonium salt was demonstrated. Organic bases, especially DMAP, in the chiral phase-transfer catalysis were used to obtain high ees.
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