Abstract
AbstractHerein, we report on the synthesis of perovskite Cs2Sn(Pb)I6 powder via a modified hydrothermal method, in which Pb2+ ions are introduced to Cs2SnI6 to optimize the semiconductor properties of double perovskite. Results indicate that the introduction of 2 at% Pb2+ into the Cs2SnI6 not only facilitates fine thermal stability, smoother surface with small grain size, expanding the scope of absorption. Thence the photovoltaic properties of Cs2SnI6 are improved where obtained a higher photocurrent density (∼ 70 µA cm−2). Combined with changes in photoelectric properties, perhaps a small amount of Pb doping plays a role in reducing the formation energy and surface energy of the compounds. On the contrary, excessive Pb doping destroys the synthesis of Cs2SnI6 and reduces the purity of the compound; thus, affecting its application. This study provides useful insights into the development of double perovskites with high stability and efficiency.
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