Abstract
Combining shear-thickening fluid (STF) with matrix material enables the creation of high-performance materials with enhanced impact resistance. However, effectively preventing STF leakage and avoiding potential reactions between the fluid and the matrix material remain notable challenges. Encapsulating STF through emulsion templating offers a viable solution to these issues. Traditional emulsion templating methods require adding extra solvents to STF to counteract the hindrance of shear-thickening on emulsification, accompanied with increased costs and environmental pollution, and difficulties in maintaining the integrity of core components. In this study, we developed STF microcapsules using a novel high-temperature Pickering double emulsion technique. Our investigation into the rheological properties of molecular sieve/diols suspensions demonstrates that the shear thickening effect could be controlled by particle concentration, surface charge of particles and solvent viscosity. Octadecyltrimethoxysilane-modified fumed silica and fumed silica were utilized as stabilizers for STF-in-paraffin primary emulsions and STF-in-paraffin-in-propylene glycol secondary emulsions, respectively. As temperature increased, droplet sizes of the primary emulsion were significantly reduced. The Pickering emulsion approach effectively preserves the STF composition by forming robust barriers at the emulsion interface with silica particles. Typical STF microcapsules were incorporated into a silicone rubber matrix, the composites exhibited a significant decrease in resilience and an enhanced impact resistance with a 20.9% reduction in maximum impact force. This study is the first to suggest the application of the high-temperature Pickering double emulsion technique for the microencapsulation of STF, offering a practical and scalable method without diluting the STF, thereby ensuring the controllability of the core components.
Published Version
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a call