Abstract
Abstract Electrochemical pre-concentration has been shown to effectively increase sample sensitivity and decrease processing time; however, the basic mechanism and optimal conditions of the technique remain unknown, specifically for lanthanides. To gain a better understanding of the mechanism of action, the aqueous solution conditions required to maximize the electrochemical pre-concentration of lanthanum (La) were studied. Parameters investigated included pH, applied potential, and ionic strength. To further optimize and elucidate the mechanism of lanthanide pre-concentration, specific interactions of lanthanum with the mercury film electrode were studied. Three possible mechanisms were proposed based on preliminary observations, including ligand bridging, hydroxide formation, and amalgamation.
Published Version
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