Abstract

Object:Geopolymers mixes were fabricated from Metakaolin (MK) and Blast Furnace Slag (BFS) waste material in the presence of sodium hydroxide and sodium silicate which were used as alkali activators. To optimize the suitable amount of slag, eleven batches were designed, mixed and homogenized for 30 min.Method:To determine the suitable amount of liquid required for pasting, normal consistency and setting time were determined. The physico-mechanical properties at different curing agesi.e. 3, 7, 28 and 90 days, were determined. X-ray diffraction and scanning electron microscope were used to investigate phase composition and microstructure.Result:To guarantee forming geopolymer gel and to check its amount, HCl extraction test was performed. Salicylic acid/methanol extraction was also performed to verify the presence and amount of Calcium Silicate Hydrate (CSH). The results revealed that calcium-rich slag (BFS) accelerated the hardening process and decreased the alkaline liquid consistency. For geopolymer without BFS, two phases, namely; un-reacted metakaolin and geopolymer gel were formed. For geopolymers with BFS, three phases were formed, namely; un-reacted metakaolin, geopolymer gel and CSH with aluminum substitution (CASH) gel. The bulk density was increased with increasing BFS and curing time. The strength was increased with increasing of BFS, reaching its maximum (about 120 MPa) for the specimen containing 70% slag, cured for 28 days.

Highlights

  • New type of un-fired ceramic materials has received attention

  • BFS used in this study, is water cooled slag supplied from Iron and Steel Factory, Helwan, Egypt

  • The bulk density increases with increasing curing time

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Summary

Introduction

New type of un-fired ceramic materials has received attention This material often refers to geopolymer or inorganic polymer. Geopolmer known as alkali activated aluminosilicate binders with the general formula M2O.mAl2O3.nSiO2, where m ≈ 1 and 2 ≤ n ≤ 6 (M usually is Na or K) [1] It forms by the reaction of an aluminosilicate material with highly concentrated alkaline solution [2]. The presence of higher amounts of Al and Si causes re-condensation of soluble ions which assemble into inorganic polymer and create amorphous network with high mechanical strength compared with other binding materials. In this polymerization process, water doesn’t consume for hydration; it has an active role as a dissolution medium. The alkali ions in the medium are connected in geoplymer network through balancing with Al and Si [3]

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