Abstract
Structure design is of great value for the performance improvement of solid oxide electrolysis cells (SOECs) to diminish the gap between scientific research and industrial application. A comprehensive multi-physics coupled model is constructed to conduct parameter sensitivity analysis to reveal the primary and secondary factors on the SOEC performance and optimal rib width. It is found that the parameters of the O2 electrode have almost no influence on the optimal rib width at the H2 electrode side and vice versa. The optimized rib width is not sensitive to the electrode porosity, thickness, electrical conductivity and gas composition. The optimal rib width at the H2 electrode side is sensitive to the contact resistance at the interface between the electrode and interconnect rib, while the extremely small concentration loss at the O2 electrode leads to the insensitivity of optimal rib width to the parameters influencing the O2 diffusion. In addition to the contact resistance, the applied cell voltage and pitch width also has a dramatic influence on the optimal rib width of the fuel electrode. An analytical expression considering the influence of total cell polarization loss, the pitch width and the contact resistance is further developed for the benefit of the engineering society. The maximum error in the cell performance between the numerically obtained and analytically acquired optimal rib width is only 0.14% and the predictive power of the analytical formula is fully verified.
Highlights
Renewable energy resources, including solar, wind, tidal, and biomass, are of great significance as the fossil energy crisis is becoming increasingly serious
We have developed a comprehensive mathematical model for the performance research of solid oxide electrolysis cells (SOECs)
The current density increase rate decreases when rib width is large enough. It finds out three main factors affecting optimal rib width at the H2 electrode side: area specific resistance (ASR) at the rib–electrode interface, the pitch width, and the applied cell voltage
Summary
Renewable energy resources, including solar, wind, tidal, and biomass, are of great significance as the fossil energy crisis is becoming increasingly serious. In the last 20 years, during the simulation of SOFC, it found out that rib width design is of great significance to improve the cell performance [15,16,17,18], which has been experimentally confirmed [19]. The authors of [17] investigated the effect of ASR between the electrode and the rib on the performance of SOFC, and conducted the rib width optimization by 2D. Reference [23] studied the influence of rib size on the performance of a reversible solid oxide cell. It takes into account the efficiency of a solid oxide fuel cell and electrolysis cell comprehensively.
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