Abstract

We design a partially aperiodic, vertically-aligned silicon nanowire array that maximizes photovoltaic absorption. The optimal structure is obtained using a random walk algorithm with transfer matrix method based electromagnetic forward solver. The optimal, aperiodic structure exhibits a 2.35 times enhancement in ultimate efficiency compared to its periodic counterpart. The spectral behavior mimics that of a periodic array with larger lattice constant. For our system, we find that randomly-selected, aperiodic structures invariably outperform the periodic array.

Highlights

  • We use large-scale simulations and machine-based optimization techniques [18,19,20,21,22,23,24,25] to design optimal, aperiodic nanowire structures with greater than 100% increase in photovoltaic efficiency compared to their periodic counterparts

  • The absorptance of the periodic array is higher than the thin film in the high-energy range, which can be attributed to reduced reflection from the top surface

  • We investigated whether aperiodic structures outperform the periodic array in general

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Summary

Introduction

“Analysis of optical absorption in silicon nanowire arrays for photovoltaic applications,” Nano Lett. L. Povinelli, “Optical absorption enhancement in silicon nanowire arrays with a large lattice constant for photovoltaic applications,” Opt. Express 17(22), 19371–19381 (2009). “Optical absorption enhancement in disordered vertical silicon nanowire arrays for photovoltaic applications,” Opt. Lett.

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