Optimal bi-planar gradient coil configurations for diamond nitrogen-vacancy based diffusion-weighted NMR experiments

Abstract

IntroductionDiffusion weighting in optically detected magnetic resonance experiments involving diamond nitrogen-vacancy (NV) centers can provide valuable microstructural information. Bi-planar gradient coils employed for diffusion weighting afford excellent spatial access, essential for integrating the NV-NMR components. Nevertheless, owing to the polar tilt of roughly 55^{circ } of the diamond NV center, the primary magnetic field direction must be taken into account accordingly.MethodsTo determine the most effective bi-planar gradient coil configurations, we conducted an investigation into the impact of various factors, including the square side length, surface separation, and surface orientation. This was accomplished by generating over 500 bi-planar surface configurations using automated methods.ResultsWe successfully generated and evaluated coil layouts in terms of sensitivity and field accuracy. Interestingly, inclined bi-planar orientations close to the NV–NMR setup’s requirement, showed higher sensitivity for the transverse gradient channels than horizontal or vertical orientations. We fabricated a suitable solution as a three-channel bi-planar double-layered PCB system and experimentally validated the sensitivities at 28.7 mathrm mT/m/A and 26.8 mathrm mT/m/A for the transverse G_{x} and G_{y} gradients, and 26 mathrm mT/m/A for the G_{z} gradient.DiscussionWe found that the chosen relative bi-planar tilt of 35^{circ } represents a reasonable compromise in terms of overall performance and allows for easier coil implementation with a straight, horizontal alignment within the overall experimental setup.