Abstract
The synthesis and resolution of (+) 578- and (-) 578-(η-C 6H 6)RuCl(Me) [Ph 2PNHCH(Me) (Ph)] is described. Insertion of anhydrous SnCl 2 into the Ru-Cl bond yielded (+) 578- and (-) 578-(η-C 6H 6)RuSnCl 3(Me)-[Ph 2PNHCH(Me) (Ph)], the stereoselectivity of which is dependent on the reaction conditions. All the new complexes were found to be configurationally stable in a wide variety of solvents up to 60°C./
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