Abstract
The fullerene–metal complexes (η2-C60)MH(CO)[(+)DIOP] (M=Ir, Rh) have been prepared by the exchange reaction of PPh3 in corresponding (η2-C60)MH(CO)(PPh3)2 for the chelate optically active ligand (+)DIOP [(+)-2,3-O-isopropylidene-2,3-dihydroxy-1,4-bis(diphenylphosphino)ethane] and their structures assigned.
Published Version
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