Abstract

AbstractPolylactic acid (PLA) is a polymer material on which biodegradability research has been the most advanced. PLA is a chiral polymer in which molecules containing asymmetric carbon atoms have a helical structure. Two optical isomers of PLA exist, PLLA (poly(L‐lactic acid)) and PDLA (poly(D‐lactic acid)). In this study, using various physical processes, we fabricated various samples such as oriented PLLA film, PLLA fiber, rolled PLLA film and forged PLLA plate. We observed a large optical rotatory power ρ in the cylindrical plate fabricated using a forging process. ρ of forged PLLA plates is 7200°/mm which is approximately 300 times larger than that of α‐quartz.

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