Abstract

Optical properties of photo-oxidized polyfluorene (PFO), which is of practical important information for PFO based polymer light emitting diodes, have been studied by photoluminescence (PL) spectroscopy. PFO thin films were oxidized by the irradiation of a He-Cd laser (1 = 325 nm) and the photo-oxidized states were characterized by optical absorption, Fourier transform infrared absorption and electron spectroscopy for chemical analysis measurements. Temperature dependence of PL intensity of PFO is well described by a thermal quenching model, from which it is found that non-radiative decay enhances by photo-oxidation and that the height of potential barrier for the singlet excited states to the oxygen-related quenching centers is ∼ 50 meV.

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