Optical properties of freestanding GaN nanomembranes using monochromated valence-EELS

Abstract

In the present study, the dielectric function of freestanding GaN nanomembranes was described using valence electron energy loss spectroscopy coupled to a monochromated electron probe in a Sub-Electron-volt Sub-Angstrom transmission electron Microscope. Such a technique has proven to be very efficient in handling nanometer-scale freestanding nanomembranes and provided local and direct measurements of optical characteristics. Indeed, core-state along with outer-shell electrons transitions were first measured in the configuration where the GaN c→-axis was normal to the transferred momentum q→. With the help of Kramers-Kroning analyses and density functional theory, critical points energies were extracted and assigned. Finally, optical data such as the real refractive index n, extinction coefficient k, absorption coefficient α and reflectivity R were numerically deduced from the real and imaginary parts of the dielectric function.