Optical experiment study on Ammonia/Methanol mixture combustion performance induced by methanol jet ignition in a constant volume combustion bomb

Abstract

Ammonia as an alternative fuel has shown great potential in reducing carbon dioxide emissions. However, the issues of high ignition temperature and unstable combustion of ammonia limit its extensive application. As an ignition energy enhanced method, the ignition chamber (pre-chamber) seems to be an effective solution to improve the combustion performance and extend the ammonia lean flammability limit. In this study, the methanol was provided as relatively high activity fuel to improve the mixture activity in the ignition chamber and main chamber. The mixture activity control method was introduced to accelerate ammonia premixed combustion. The visualization experiment compounded with shadow method was applied to investigate. Results showed that the methanol fueled ignition chamber as jet ignition model reduced the combustion duration by almost half compared to spark ignition method. The methanol jet flame propagation formatted multiple zones of ignition and combustion in the main chamber. The ammonia combustion speed shifted from being determined by laminar flame propagation speed to being determined by jet velocity. The methanol jet velocity is related to the methanol energy substitution ratio and nozzle diameter of the ignition chamber. A 2 % methanol energy substitution ratio is optimized for the lean condition of Φ = 0.8 compared to 1 % methanol energy substitution ratio achieve for the condition Φ = 1.0 in the main chamber. When 50 % methanol (energy) was added in the main chamber, the activity thermo-atmosphere improvement induced the combustion duration to decrease by 43.8 % and 51.9 % at equivalent ratios of 1.0 and 0.8, respectively, compared to pure ammonia. The small nozzle diameter of ignition chamber can improve the jet velocity, however it caused the methanol combustion flame quenching leading to unstable combustion phenomenon. A 3 mm nozzle diameter achieved a short combustion duration compared to 4.5 mm and 6 mm nozzle diameter.