Optical characterization of 316L stainless steel coated with sol–gel titania

Abstract

In this work 316L stainless steel substrates were coated with sol–gel derived films by means of the dip-coating technique. Titanium isopropoxide and ethanol were used as chemical precursor and solvent, respectively. The dip-coating step was performed using withdrawal speeds of 6mm/min, 30mm/min, and 60mm/min. Next, the samples were heat treated in air for 30min at 100°C, 300°C, and 400°C. The processed composites were examined by FTIR and UV–vis spectroscopies. We observed that the materials prepared in this work can exhibit a variety of colors depending on the heat treatment temperature, withdrawal speed, and precursor:solvent molar ratio used in their processing. It is an important finding since this behavior could lead to architectural application of these materials. We believe that the changes observed in the UV–vis spectra and the colors of these samples could be related to the variation of the coating thickness as the processing conditions were modified. FTIR tests revealed that the ratio between the intensities of features ascribed to hydroxyl groups and TiO bonds decreased as the heat treatment temperature was increased. On the other hand, the ratio between bands related to TiOTi and TiO bonds decreased when the heating temperature was raised from 100°C to 300°C.