Optical and spectroscopic studies of potassium p-nitrophenolate dihydrate crystal for frequency doubling applications

Abstract

Non centrosymmetric potassium p-nitrophenolate dihydrate single crystals have been grown by employing the technique of slow solvent evaporation from aqueous solution by slightly adjusting the pH and growth temperature. The grown crystals have been identified from single crystal XRD analysis, FTIR and FT Raman spectroscopic techniques. The high resolution X-ray diffraction experiments substantiate good quality of the title material. Between 510 and 2000 nm, the material is observed to be nearly transparent allowing it to be explored for potential use in device fabrication. In addition, the photoluminescence spectrum of the grown crystal at room temperature shows a stable broad violet-blue emission around the 383–550 nm wavelengths with the maximum centered at 436 nm. Owing to its excellent non linear figure of merit and strong PL emission, the title crystal can have technological applications in opto-electronic devices.