Abstract
Chromium containing mica is called fuchsite. Fuchsite originating from the Nellore district of India containing 3.37 wt.% of chromium is used in the present study. Optical absorption and EPR studies were carried out at room temperature (RT). The optical absorption spectrum gives energies at 14 925, 15 070, 15 715, 16 400, 17 730 and 21 740 cm −1, which are attributed to spin-allowed transitions for Cr 3+ in an octahedral symmetry. EPR spectra show a strong resonance with g=1.98 along with two sets of weak resonances which are attributed to two sets of chromium in the sample. The zero field splitting parameter ( D) is almost zero. These spectra are due to Cr 3+ in the mineral. The NIR spectrum is due to hydroxyl ions in the sample.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
More From: Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.