Operando analysis of in-plane heterogeneity for the PEM electrolyzer cell: Mappings of temperature and current density

Abstract

The internal multi-physical fields of a proton exchange membrane electrolyzer cell (PEMEC) are affected by various factors, exhibiting an intricate coupling state. During electrolysis process, the complexity manifests as heterogeneous distribution of in-plane temperature and current density, potentially leading to local hot spots and performance degradation. Such challenges pose threats to the lifespan and operational safety of PEMEC. This study developed temperature measurement endplates and segmented printed circuit board (PCB), enabling operando measurement of in-plane temperature and current density distribution inside a 25 cm2 lab-scale PEMEC. The mappings of temperature and current density were plotted, and the in-plane heterogeneity was assessed by the introduced indexes. The results indicate that variations in operational parameters affect the balance among cell heat production, heat dissipation, and heat input in the flow area, leading to temperature distribution heterogeneity. The migration mechanism of high-temperature zone is elucidated. Factors such as water-gas flow and local conduction contribute to the heterogeneity in current density distribution. Additionally, specific operating conditions including cold and warm start-up, and water starvation are taken as cases, and a detailed analysis is conducted on the dynamic behaviors of current and temperature distribution and the heterogeneity evolution. This work not only provides experimental evidence for the electrical-thermal characteristics inside the PEMEC but also offers insights for local performance evaluation and operation fault diagnosis in practical applications.