Abstract
ABSTRACTThis work introduces cationic ring opening polymerization of polyepichlorohydrin (PECH) produced under various reaction conditions (set temperature: −10 to 40°C, [C]/[I] ratio: 0.1–1, monomer feed rate: 1–4 mL/min). In addition, a correlation between the exothermic reaction temperature and the performance of the PECH was obtained by utilizing a reaction temperature monitoring system, GPC, 1H‐NMR, and FTIR. During the polymerization, an induction period which affects the polydispersity was observed below 10°C. At lower temperatures and lower [C]/[I] ratios, a higher induction period was observed. The monomer feed rate did not affect the induction period but it highly affected the polydispersity when the induction period occurred. The total molecular weight of PECH increased with decreasing set temperature even though the amount of low molecular weight cyclic oligomer increased. © 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014, 131, 39912.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
