One-pot synthesis of fluorescent non-conjugated polymer dots for Fe3+ detection and temperature sensing.

Abstract

The facile preparation of highly fluorescent polymer dots (PDs) still attracts substantial interest. Here, temperature/Fe3+ dual-responsive PDs are synthesized under mild conditions via the amidation reaction and self-assembly between hyperbranched polyethyleneimine and 5-aminosalicylic acid. The prepared PDs display strong green fluorescence with quantum yield of 15.5% and 53.3% in water and dimethylsulfoxide, respectively. The PDs also possess unique features, including excellent solubility, solvent polarity-dependent emission, remarkable photostability, as well as good salt-tolerance. Interestingly, the fluorescence intensity of PDs exhibits a reversible and sensitive response to temperature within 20-65°C, which renders the PDs useful as a thermometer probe. Importantly, Fe3+ ion has the specific coordination ability toward the surface groups of PDs, leading to the aggregation and fluorescence quenching of PDs. Thus, the PDs are employed as a fluorescence probe for sensitive detecting Fe3+. The fluorescent intensity linearly decreases with increasing Fe3+ from 2 to 60μM. Besides, Fe3+ concentration in river water samples is successfully assayed with this developed probe. The non-conjugated PDs with facile preparation, sensitive response to temperature and Fe3+ may hold potential applications in environmental monitoring.