One-Dimensional CoMoP Nanostructures as Bifunctional Electrodes for Overall Water Splitting.

Abstract

As high-quality substitutes for conventional catalysts, the bifunctional catalytic properties of the coating of transition-metal-based materials are pivotal for improving water-splitting efficiency. Herein, cobalt-molybdenum bimetallic phosphide nanofibers (CoMoP NFs) were synthesized via a series of facile strategies, which are divided into pyrolysis electrospun PAN and metal salts, to obtain one-dimensional morphology and a gas-solid phosphating precursor. The obtained CoMoP NFs catalyst has superior catalytic activity performance in 1M KOH. Serving as an oxygen evolution reaction (OER) catalyst, the electrode of the CoMoP NFs affords different kinds of current densities at 50 mA cm-2 and 100 mA cm-2, with low overpotentials of 362 and 391 mV, respectively. In addition, the hydrogen evolution reaction (HER) performance of the CoMoP NFs mainly shows when under a low overpotential of 126 mV, which can deliver a current density of 10 mA cm-2. In order to further detect the stability of the catalyst, we used multiple cyclic voltammetry and chronopotentiometry tests for OERs and HERs, which maintain performance and carry a current density of 10 mA cm-2 for longer. As an integrated high-performance bifunctional electrode for overall water splitting, the CoMoP NFs only require 1.75 V@10 mA cm-2 for 40 h. This work highlights a facile method to create an electrocatalyst with fiber nanostructures which possesses excellent activity as an alkaline electrolyte.