One-pot synthesis of MoS2 nanoflowers for thermal energy storage applications

Abstract

In this study, flower-like MoS2 nanospheres were synthesized via a facile hydrothermal route. The morphological and phase analysis confirmed the formation of polycrystalline MoS2 nanoflowers assembled by lamellar nanosheets. A novel shape-stabilized phase change material was fabricated by imprisoning different concentrations of MoS2 into myristic acid. It was observed from the experimental results that the duration of melting and cooling rates for PCM of 0.25 wt%, 0.5 wt%, 0.75 wt%, 1 wt%, 1.25 wt% increased as compared to pristine counterparts. 1 wt% had the highest heat transfer rate, with a value of 9.4% and 52.81% for melting and cooling, respectively. The result from analytical technique showed there was no chemical reaction between MoS2 and myristic acid even after multiple cycles. Since this unique MoS2 based composite has indicated good thermal reliability for latent-heat storage, and release, this composite can be considered as an appropriate PCM for thermal energy storage applications.