Abstract

Exploring the structure of low-dimensional materials is a key step towards a complete understanding of condensed matter. In recent years, owing to the fast developing of research tools, novel structures of many elements have been reported, revealing the possibility of new properties. Refining the investigation of one-dimensional atomic chain structures has thus received a great amount of attention in the field of condensed matter physics, materials science and chemistry. In this paper, we review the recent advances in the study of confined structures under nanometer environments. We mainly discuss the most interesting structures revealed and the experimental and theoretical methods adopted in these researches, and we also briefly discuss the properties related to the new structures. We particularly focus on elemental materials, which show the richness of one-dimensional structures in vacuum and in nanoconfinement. By understanding the binding and stability of various structures and their properties, we expect that one-dimensional materials should attract a broad range of interest in new materials discovery and new applications. Moreover, we reveal the challenges in accurate theoretical simulations of one-dimensional materials in nanoconfinement, and we provide an outlook of how to overcome such challenges in the future.

Highlights

  • In this paper, we review the recent advances in the study of confined structures under nanometer environments

  • We particularly focus on elemental materials, which show the richness of one-dimensional structures in vacuum and in nanoconfinement

  • We reveal the challenges in accurate theoretical simulations of one-dimensional materials in nanoconfinement, and we provide an outlook of how to overcome such challenges in the future

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Summary

Introduction

低维限域结构中水与物质的输运 Water and mass transport in low-dimensional confined structures 物理学报. 纳米结构超疏水表面冷凝现象的三维格子玻尔兹曼方法模拟 Three-dimensional lattice Boltzmann modeling of droplet condensation on superhydrophobic nanostructured surfaces 物理学报. 基于一维弹道导体的三端纳米线制冷机的性能优化 Performance optimization of three-terminal nanowire refrigerator based on one-dimensional ballistic conductor 物理学报. 近年来, 随 着技术的发展, 实验上成功制备出了原子数更多的 碳链结构, 如 Shi 等 [9] 于 2016 年在碳纳米管中合 成了最长由 6000 多个碳原子构成的多烯型碳链, 并通过透射电子显微术确认了它的稳定性.

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