One-dimensional photonic crystals based on porous anodic alumina: Optical and morphology changes under thermal and chemical treatments

Abstract

One-dimensional photonic crystals (1D PCs) based on porous anodic aluminium oxide (AAO) are promising for light manipulation and sensing. As-prepared AAO, being amorphous material, suffers degradation in acidic and alkaline media. It is commonly known that the chemical stability of AAO increases drastically after thermal treatment. Here, the effect of annealing up to 1200 °C on the morphology and the optical properties of AAO PCs is studied. The two-step crystallization of as-prepared AAO at 860 and 1190 °C leads to a two-step blue shift of the central wavelength of photonic band gap (PBG) and the decrease in PBG depth, whereas the Q-factor of the PBG enhances. The observed changes in optical transmittance spectra of PCs are mainly attributed to the increase in pore diameter, the formation of crystalline particles of alumina polymorphs, and the removal of impurities. Annealed AAO PCs demonstrate much higher stability of optical parameters during exposure in acidic media compared to the as-prepared ones. Thermal treatment at 600 °C results in 30% decrease in the rate of the PBG shift during chemical etching. Furthermore, AAO crystallization into a mixture of low-temperature alumina polymorphs at 860 °C leads in a negligible change in transmittance spectra even after chemical etching in 1 M HCl for 75 h. The excellent stability achieved for the annealed AAO PCs in aggressive media proves the perspectives of their application as the optical sensors with long-term stability.