On the wide range of mechanical properties of ZTA and ATZ based dental ceramic composites by varying the Al2O3 and ZrO2 content

Abstract

Abstract In this work the influence of pressureless sintering on the Vickers hardness and fracture toughness of ZrO 2 reinforced with Al 2 O 3 particles (ATZ) and Al 2 O 3 reinforced with ZrO 2 particles (ZTA) has been investigated. The ceramic composites were produced by means of uniaxial compacting at 50 MPa and the green compacts were heated to 1250 °C using a heating rate of 10 °C min −1 , then to 1500 °C at 6 °C min −1 and maintained at this temperature during 2 h. After sintering, relative density over 94%, hardness values between 9.5 and 21.9 GPa, and fracture toughness as high as 3.6 MPa m 1/2 were obtained. The presence of TZ-3Y particles on the grain boundaries suggests that they inhibit notably the alumina grain growth. The grain sizes of pure Al 2 O 3 and TZ-3Y as well as Al 2 O 3 and TZ-3Y in the 20 wt% Al 2 O 3 +80 wt% TZ-3Y composite were 1.27 ± 0.51 μm, 0.57 ± 0.12 μm, 0.65 ± 0.19 μm and 0.41 ± 0.14 μm, respectively. The 20 wt% Al 2 O 3 + 80 wt% ZrO 2 + 3 mol% Y 2 O 3 (TZ-3Y) composite showed a hardness of 16.05 GPa and the maximum fracture toughness (7.44 MPa m 1/2 ) with an average grain size of 0.53 ± 0.17 μm. On the other side, the submicron grain size and residual porosity seem to be responsible for the high hardness and fracture toughness obtained. The reported values were higher than those obtained by other authors and are in concordance with international standards that could be suitable for dental applications.