Abstract
Abstract. In submitting data to the World Meteorological Organization (WMO) World Ozone and Ultraviolet Data Center (WOUDC), numerous ozonesonde stations include a correction factor (CF) that multiplies ozone concentration profile data so that the columns computed agree with column measurements from co-located ground-based and/or overpassing satellite instruments. We evaluate this practice through an examination of data from four Japanese ozonesonde stations: Kagoshima, Naha, Sapporo, and Tsukuba. While agreement between the sonde columns and Total Ozone Mapping Spectrometer (TOMS) or Ozone Mapping Instrument (OMI) is improved by use of the CF, agreement between the sonde ozone concentrations reported near the surface and data from surface monitors near the launch sites is negatively impacted. In addition, we find the agreement between the mean sonde columns without the CF and the ground-based Dobson instrument columns is improved by ~1.5 % by using the McPeters et al. (1997) balloon burst climatology rather than the constant mixing ratio assumption (that has been used for the data in the WOUDC archive) for the above burst height column estimate. Limited comparisons of coincident ozonesonde profiles from Hokkaido University with those in the WOUDC database suggest that while the application of the CFs in the stratosphere improves agreement, it negatively impacts the agreement in the troposphere. Finally and importantly, unexplained trends and changing trends in the CFs appear over the last 20 years. The overall trend in the reported CFs for the four Japanese ozonesonde stations from 1990–2010 is (−0.264 ± 0.036) × 10−2 yr−1; but from 1993–1999 the trend is (−2.18 ± 0.14) × 10−2 yr−1 and from 1999–2009 is (1.089 ± 0.075) × 10−2 yr−1, resulting in a statistically significant difference in CF trends between these two periods of (3.26 ± 0.16) × 10−2 yr−1. Repeating the analysis using CFs derived from columns computed using the balloon-burst climatology, the trends are somewhat reduced, but remain statistically significant. Given our analysis, we recommend the following: (1) use of the balloon burst climatology is preferred to a constant mixing ratio assumption for determining total column ozone with sonde data; (2) if CFs are applied, their application should probably be restricted to altitudes above the tropopause; (3) only sondes that reach at least 32 km (10.5 hPa) before bursting should be used in data validation and/or ozone trend studies if the constant mixing ratio assumption is used to calculate the above burst column (as is the case for much of the data in the WOUDC archive). Using the balloon burst climatology, sondes that burst above 29 km (~16 hPa), and perhaps lower, can be used; and (4) all ozone trend studies employing Japanese sonde data should be revisited after a careful examination of the impact of the CF on the calculated ozone trends.
Highlights
Ozonesondes have been a stalwart technology in atmospheric chemistry analyses for many decades
This paper has provided an analysis of the application of the correction factor (CF) for ozonesonde profile data based on observations from the four Japanese ozonesonde stations, Total Ozone Mapping Spectrometer (TOMS) and Ozone Mapping Instrument (OMI) overpass column data, ground-based Dobson instrument column data, and surface monitor data from sites nearby to the ozonesonde stations
We find that while CFs based on sonde column to Dobson instrument column ratios result in better agreement with the satellite observations, the agreement between the sonde reported ozone concentration measurements and those of the nearby surface monitors deteriorates
Summary
Ozonesondes have been a stalwart technology in atmospheric chemistry analyses for many decades. The electrical current so produced is directly related to the ozone concentration reported This type of cell was first developed by Kobayashi and Toyama (1966) and has been used almost exclusively by the Japanese stations from the initiation of their observations until late 2009 at Sapporo and Tsukuba and late 2008 at Naha, at which point these stations switched to the two-cell ECC that is employed by most other ozonesonde stations around the world. Ozonesonde profiles in this archive most frequently apply correction factors (CF) to the profiles that results in better agreement between total columns computed from the sonde profiles and correlated ozone measurements (e.g., Dobson and Brewer spectrophotometers, satellite overpass data). The final section offers some conclusions derived from this study as well as some recommendations for the use of CF data with ozonesonde profiles
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