Abstract

Extracts with tri- n-octylammonium chlorocomplexes of Sn(IV) of various compositions, included the N-deuterated compounds, were prepared and investigated by IR spectroscopy and conductivity measurements. Three Sn(IV) complexes were found: (TOAH +) 2SnCl 6 2− (2:1-complex), TOAH +SnCl 5 − (1:1-complex) and a complex with the stoichiometric ratio TOA:Sn(IV) > 2. The cation of the latter contains the groups (TOAH…Cl…HTOA) + and TOAH + and that species is supposed to be a 3:1-complex (TOAH…Cl…HTOA) +TOAH +SnCl 6 2−.

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