Abstract

Abstract Halogenodithiocarbamato mercury(II) complexes [HgX(Et2NCSS)] and [HgX(PipCSS)] (Pip[dbnd]piperidyl; X[dbnd]C1, Br or I) have been synthesized by the reaction of mixed benzoic-dithiocarbamic anhydride with mercury(II) halides in acetone. The complexes were characterized by chemical analyses, conductance measurements, molecular weight determinations, magnetic susceptibility measurements, and electronic and IR spectral studies. The complexes were dimeric in benzene solution. The IR spectra indicate monodentate bonding for the dithiocarbamate ligand and the absence of halogen bridges in these complexes.

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