Abstract
Measurements of oxygen activity in molten copper, Cu-Sn, and Cu-Ag alloys at 1135°C have been made utilizing the solid-state electrolyte technique. The activity coefficient of oxygen in molten copper at low oxygen levels (<0.1 pet) was found to be 0.12. The interaction parameters of silver and tin on oxygen were found to be eOAg = 4.52 and eOSn =-10.5. Comparison of experimental data with solution models revealed that the behavior of oxygen in Cu-O-Ag alloys is in accordance with predictions of Alcock and Richardson’s quasichemical model when a coordination number between 1 and 4 is assumed, depending on the silver and oxygen content. Furthermore, agreement with Belton’s quasichemical model based on the assumption of Ag-O dipoles serves to strengthen the evidence for the existence of Ag-O species in solution. The behavior of oxygen in the Cu-O-Sn system also shows better agreement with the quasichemical model than with the random model, with low coordination numbers favored in dilute tin solutions, increasing to larger values in Cu-60 Sn solutions.
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