Abstract
The second differences in Hartree-Fock SCF energies are found to be constant for isoelectronic series.The 1/Z perturbation treatment of the Hartree-Fock equations allows us to relate these differences to the numerical findings. A recurrence relationship for electronic total energies is obtained and from its application very good agreement with SCF data is found.
Published Version
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have