Abstract
We study the correlation structure of separable and classical states in $2\times2$-~and~$2\times3$-dimensional quantum systems with fixed spectra. Even for such simple systems the maximal correlation - as measured by mutual information - over the set of unitarily accessible separable states is highly non-trivial to compute; however for the $2\times2$ case a particular class of spectra admits full analysis and allows us to contrast classical states with more general separable states. We analyse a particular entropic binary relation on the set of spectra and prove for the qubit-qutrit case that this relation alone picks out a unique classical maximum state for mutual information. Moreover the $2\times3$ case is the largest system with such a property.
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