On the impedance of galvanic cells: XXV. The double-layer capacitance of the dropping mercury electrode in 1 M HCl, 7.5 M HCl and 5.2 M HClO 4 and the kinetic parameters of the hydrogen electrode reaction as a function of temperature in these solutions

Abstract

The impedance of the dropping mercury electrode in aqueous solutions in 1 M HCl, 7.5 M HCl and 5.2 M HClO4, saturated with hydrogen at one atmosphere was measured at temperatures between −39° and +72° both in and outside the potential region where the electrode reaction, e+H+ H2, proceeds.