Abstract

The oxidation behavior of a niobium-bearing high nickel-chromium alloy, widely used in the petrochemical industry, is systematically studied at 800 °C using a combination of transmission electron microscopy and atom-probe tomography experimental techniques and thermodynamic calculations. Oxidation leads to complex surface microstructures consisting of a protective chromia layer, an amorphous SiO2 (silica) layer, Fe- and Ni-rich metallic mushroom-like austenitic protrusions/precipitates, and sub-oxide voids with highly faceted surfaces. The thermodynamic equilibrium oxides of this alloy are studied as a function of oxygen activity using Thermo-Calc and compared to the observed microstructures. The growth kinetics of oxide layers are studied in detail.

Full Text
Paper version not known

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call

Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.