Abstract

In this work, we propose a non-linear differential equation of Riccati-type, where the standard partition function Z(T) is taken as its particular solution leading to their generalization Zg(T); from there, other related statistical thermodynamic functions are generalized. As an useful application of our proposal, other thermodynamic functions, namely, the internal energy, heat capacity, Helmholtz free energy and entropy, associated to the model of the ideal monatomic gas in D-dimensions are generalized. According to our results, thermodynamic properties derived from the standard partition functions by means of ordinary statistical mechanics are incomplete. In fact, although asymptotically with the increasing of temperature the generalized statistical thermodynamic functions reduce to the standard ones, these contain an extra term which is dominant at very low temperature indicating that standard findings should be corrected.

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call

Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.