Abstract

Thermodynamics relations have been considered under which gas inclusions may form in melts (closed systems), due to both volatility of components and the presence of dissolved gases. It has been shown that in the melts with sufficient volatility of components, gas inclusions may form under equilibrium conditions if the ampoule is wetted well by the melt, whereas in case of low wettability they form under non-equilibrium state only. The foaming in the tellurium-selenium system has been analysed (“Pirin”, KP-4 experiment). In the melts containing dissolved gases, gas inclusions form under conditions of deviation from equilibrium and it is the main mechanism of outgassing. It has been demonstrated that the melt foaming method using hydrid compounds may be applied to the materials exhibiting a hysteresis of temperature dependence of diluted hydrogen concentration. Production of foam aluminium under zero gravity state has been considered as an example (“Pirin”, SP-3 experiment).

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