Year-end Sale % OFF 
Abstract
Electron paramagnetic resonance of Mn(II) ion doped in bis (ammonium) pentafluorostibnate is reported. Local charge compensation is proposed as the reason for the doubling of the expected single site. A ±20° rotation of the MnF3−5 moeity about the crystallographic a axis has been attributed to charge compensation processes. The D tensor is found to have the values Dzz=0.0358 cm−1, Dyy=−0.028 62 cm−1, Dxx=−0.007 26 cm−1; the Mn hyperfine coupling is found to be −0.0095 cm−1. The apical flourine does not give resolved hyperfine coupling, while the four basal flourine atoms give hyperfine couplings in the range amax=0.0018 cm−1, amin=0.0015 cm−1.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
