On-Line Mass Spectrometry Measurement of Fission Gas Release From Nuclear Fuel Submitted to Thermal Transients

Abstract

The work presented in this paper has been performed in the framework of a joint research program between Aix-Marseille University and CEA Cadarache. The aim is to develop a mass spectrometer (MS) device for the MERARG facility. MERARG is devoted to the study of fission gas release measurement, from nuclear fuels submitted to annealing tests in high activity laboratory such as LECA-STAR, thanks to gamma spectrometry. The mass spectrometer will then extend the measurement capability from the $\gamma $ -emitting gases to all the gases involved in the release in order to have a better understanding of the fission gas release dynamics from fuel during thermal transients. Furthermore, the mass spectrometer instrument combines the capabilities and performances of both on-line (for release kinetic) and off-line implementations (for delayed accurate analysis of capacities containing total release gas). The paper deals with two main axes: 1) the modelling of gas sampling inlet device and its performance and 2) the preliminary MS qualification/calibration results. The inlet device samples the gas and also adapts the pressure between MERARG sweeping line at 1.2 bar and mass spectrometer chamber at high vacuum. It is a two-stage device comprising a capillary at inlet, an intermediate vacuum chamber, a molecular leak inlet and a two-stage pumping device. Pressure drops, conductance and throughputs are estimated both for mass spectrometer operation and for exhaust gas recovery. The time constant for gas renewal is very low and estimated at about 1 s. Possible gas segregation is also estimated and device modification is proposed to attain a more accurate calibration. Preliminary experimental results obtained from a standard gas bottle show that the quantitative analysis at a few ppm level can be achieved for all isotopes of Xe as well as masses 2 and 4 u.