Abstract
A system involving homopolymerisation of a 3-functional monomer has been studied by using an off-lattice long-range percolation model. The elementary reaction steps were controlled by substitution effects and by local concentrations of units. The latter were controlled by setting a constant value to a range-of-reaction parameter called the capture radius. The critical conversion at gelation in the system turned to the classical one as the value of capture radius increased.
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