Of ZnO Nanoparticle using Sandoricum Koetjape Peel Extract as Bio-stabilizer under Microwave Irradiation

Abstract

The use of sentul (Sandoricum koetjape) peel extract as a biostabilizer in the synthesis of zinc oxide (ZnO) nanoparticles has been carried out as an environmentally friendly production. This research was conducted by reacting a 0.2 M of Zn precursor (zinc nitrate hexahydrate) solution with Sentul peel extract (10g/l). The samples were varied based on the ratio of the volume of the Zn solution to the Sentul peel extract, i.e., 1:4, 2:3, 1:1, 3:2, and 4:1 where each sample was assigned a ZSk initial code. The ZnO synthesis used a microwave technique with a power of 360 Watt. Morphological, structural, optical absorption, and functional groups were analyzed based on the results of the characterization of SEM, XRD, UV-Vis, and FTIR Spectroscopy. SEM images show the morphology of ZnO particles in the form of semi-hollow spheres and macaron-like shapes. The particle size decreases with the addition of the volume of the Zn solution. The XRD diffraction pattern shows the diffraction peaks that correspond to the hkl plane of the wurtzite hexagonal structure of ZnO. The highest optical absorption of the UV-Vis spectrum occurred in the wavelength range of 300-360 nm. The FTIR spectrum represents the involvement of the O-H functional groups derived from the polyphenolic compound of sentul peel extract.