Occurrence of particle‐bound polysulfides and significance of their reaction with organic matters in marine sediments

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Inorganic polysulfides (Sn2−, where n > 1) contribute to the incorporation of sulfur into organic matter in reducing sediments, especially when conditions exist for partial oxidation of sulfide. Inorganic polysulfides have been assumed previously to exist only in the aqueous phase. Our results suggest that a significant fraction of inorganic polysulfides is bound to the particulate‐phase of sediments and can react with carbon‐carbon unsaturated bonds in organic matter, thereby attaching it to the particulate phase through polysulfide linkages. This mechanism may affect the bioavailability of the reactive organic matter in sediments and hence may play an important role in the preservation of organic matter in anoxic marine sediments.