Abstract
The (1, 0) band in the b 4Σ −– a 4Π 5/2 system of the SO + cation ion has been observed in the range of 12 600–12 800 cm −1 using optical heterodyne velocity modulation spectroscopy in an AC glow discharge of He/SO 2 mixture. Rotational analysis results in close to a three orders of magnitude improvement in the molecular constants.
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