Abstract
Surface-induced profiles of both nematic and smectic order parameters in a nematic liquid crystal, ranging from an orienting substrate to "infinity," were evaluated numerically on the basis of an extended Landau theory. In order to obtain a smooth behavior of the solutions at "infinity," a boundary energy functional was derived by linearizing the Landau energy around its equilibrium solutions. We find that the intrinsic wave number of the smectic structure, which plays the role of a coupling between nematic and smectic order, strongly influences the director reorientation. Whereas the smectic order is rapidly decaying when moving away from the surface, the uniaxial nematic order parameter shows an oscillatory behavior close to the substrate, accompanied by a nonzero local biaxiality.
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