Numerical simulation on flow and reaction characteristics for catalytic region in helium-heated steam reformer coupled with HTR-10

Abstract

In this paper, one dimension steady-state and pseudo-homogeneous model of the hydrogen production reformer in the steam methane reforming (SMR) process using the high temperature gas-cooled test reactor of 10 MW (HTR-10) as heat source (HTR-10/SMR) is simulated based on the semi-coupled solution method using matlab2016b. Firstly, The axial variations of hydrogen production performance including temperature (T2), methane conversion rate (XCH4), carbon monoxide conversion rate (XCO) and hydrogen production per mole methane (YH2/CH4 or total hydrogen production (YtH2)) as well as thermal efficiency (η) are investigated. Then, it is noted that YH2/CH4 decreases from 2.92 mol H2/mol CH4 to 2.53 mol H2/mol CH4. However, YtH2 increases from 2.33 kmol/h to 3.23 kmol/h with the increase of the inlet process gas flow rate (F2inlet) from 4 kmol/h to 6 kmol/h. Finally, YtH2 increases with steam to carbon ratio (S) when S < 4 and decreases when S > 4. The maximum value of YtH2 with 3.03 kmol/h is obtained at S = 4. Especially, XCH4, XCO, YH2/CH4 and η are in the range of 70.54%–90.78%, 38.56%–54.30%, 2.50–3.07 mol/mol CH4 and 54.55%–64.57%, respectively, when T3_inlet is in the range of 850–950 °C. The effect of the process gas temperature and pressure on the system performance can be neglected.