Numerical analysis of hydrogen storage in lined rock cavern under high pressure and its implications to hydrogen embrittlement

Abstract

Underground hydrogen storage could provide buffer capacity to store the excess energy from renewable resources. A lined rock cavern (LRC) is one of the hydrogen geologic storage site options. It offers great flexibility because it does not rely on the existence of salt caverns, aquifer formations or depleted hydrocarbon reservoir fields. However, many important aspects have to be investigated before its full-scale implementation, among them (1) the effect of spatial variation of rock mass properties and (2) hydrogen embrittlement on the steel lining. We present a numerical study on these two aspects by simulating field tests at a pilot LRC project. For the effect of rock heterogeneity, we assign a spatial variation of elastic properties based on the Gaussian covariance model. The results show a good agreement with the field measurements. The spatial correlation length of rock mass elastic properties only has a minor impact on the cavern surface deformation. Regarding hydrogen embrittlement, our simulations predict a significant hydrogen diffusion in the low alloy steel (S355) lining after ∼2 months of operation. The fracture simulations show little fracture propagation even after 10 years of contact with hydrogen gas. However, the product loss may be too high for the low alloy steel (S355). We would recommend the use of stainless steel to inhibit the hydrogen diffusion. We show that advanced numerical models are powerful tools to ensure the safety of hydrogen storage in LRCs.