Abstract
1. When catalyzed by chlorine anion or pyridine, alkyl- or arylsulfenyl chlorides add to perfluoroisobutylene or to methyl perfluoromethacrylate by the nucleophilic mechanism. 2. Perfluoroisobutylene when reacted with either trichloromethyl- or chlorocarbonylsulfenyl chloride in the presence of chlorine anion adds chlorine at the multiple bond.
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