Abstract
Catalytic action of carboxamides at benzoyl chloride hydrolysis in acetonitrile at 25°C occurs by nucleophilic mechanism. Its first stage consists in reversible interaction between amides and substrate. The rate constants of the direct reaction were determined which characterized the oxygen-nucleophilic reactivity of amides toward benzoyl chloride. The assumption was confirmed that bimolecular addition of benzoyl chloride to the carbonyl oxygen of amides occurred in cyclic transition states.
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